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Definition: Organic chemistry is the study of carbon-based compounds. Unlike the older view that only substances from living organisms were “organic,” today we understand that many such compounds can be synthetically produced from inorganic precursors.
Carbon’s unique ability to catenate (link together) enables the formation of extensive straight, branched, or cyclic chains, often including atoms such as hydrogen, oxygen, nitrogen, and halogens. It also forms single, double, or triple covalent bonds, which greatly increases the diversity of organic molecules.
Hydrocarbons, derived from the words “hydro” (water) and “carbon,” are compounds composed solely of carbon and hydrogen. They form the primary fraction of crude oil—a thick, dark, and viscous liquid. Crude oil is a complex blend that includes gaseous, liquid, and solid alkanes (which can make up to 90% of petroleum), as well as alkenes, cyclic compounds, and aromatic molecules like benzene, ethylbenzene, and naphthalene. In some cases, crude oil also contains oxygen, nitrogen, and sulfur; for example, Nigerian “sweet crude” has minimal sulfur content, thus resulting in reduced pollution.
Hydrocarbons can be broadly grouped as saturated or unsaturated. In saturated hydrocarbons (also known as alkanes), every carbon atom’s four bonds are completely fulfilled by single covalent bonds. In contrast, unsaturated hydrocarbons, such as alkenes and alkynes, feature one or more double or triple bonds and are prone to addition reactions.
Alkanes are compounds that consist solely of carbon–carbon (C–C) and carbon–hydrogen (C–H) single bonds. Their general formula is CnH2n+2, where n represents the number of carbon atoms. They are also known as paraffins.
Unsaturated compounds include alkenes (with at least one double bond) and alkynes (with at least one triple bond). Their formulas are typically CnH2n (for alkenes) and CnH2n-2 (for alkynes). The key difference lies in the type and number of bonds between the carbon atoms.
Cyclic hydrocarbons are those in which the terminal carbon atoms of an open chain connect to form a ring. Aromatic hydrocarbons, such as benzene, possess a unique ring structure with resonance stabilization. Additionally, haloalkanes form when one or more hydrogen atoms in an alkane are replaced by halogen atoms (e.g., Cl, Br, F).
Alcohols, also known as alkanols, are organic compounds containing one or more hydroxyl (-OH) groups. They are classified based on the number of hydroxyl groups (monohydric vs. polyhydric) and exhibit distinct physical and chemical properties.
Alcohols are divided into monohydric (one -OH group) and polyhydric (more than one -OH group) categories. Their physical properties, such as boiling point and solubility, vary with molecular weight and structure, while chemically they can undergo oxidation, dehydration, and substitution reactions.
Alkanoic acids (commonly known as carboxylic acids) contain a carboxyl (-COOH) functional group. They can be simple or substituted, with dicarboxylic and aromatic acids as special categories. These acids are integral in biological systems and industrial processes.
Alkanoic acids are typically produced by the oxidation of aldehydes or through the hydrolysis of nitriles. They participate in neutralization, esterification, and polymerization reactions, making them essential in both nature and industry.
This section outlines the systematic naming of organic molecules. Names are constructed using a prefix (denoting the number of carbon atoms) and a suffix (indicating the compound’s functional group). For instance:
| Number of Carbons | Prefix |
|---|---|
| 1 | meth- |
| 2 | eth- |
| 3 | prop- |
| 4 | but- |
| Compound Class | Suffix |
|---|---|
| Alkanes | -ane |
| Alkenes | -ene |
| Alcohols | -ol |
| Carboxylic Acids | -oic acid |
Note: For fluidity in pronunciation, an extra syllable is often inserted (e.g., “ethanol” rather than “ethol”).
Question 1: Which term best describes compounds composed solely of carbon and hydrogen?
Question 2: In IUPAC nomenclature, what suffix is used for alkenes?
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